WO1996019922A1 - Method and arrangement for cooling of a pumpable liquid with or without particles - Google Patents
Method and arrangement for cooling of a pumpable liquid with or without particles Download PDFInfo
- Publication number
- WO1996019922A1 WO1996019922A1 PCT/SE1995/001556 SE9501556W WO9619922A1 WO 1996019922 A1 WO1996019922 A1 WO 1996019922A1 SE 9501556 W SE9501556 W SE 9501556W WO 9619922 A1 WO9619922 A1 WO 9619922A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- liquid
- gas
- cooling
- condensed
- particles
- Prior art date
Links
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23D—EDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS, COOKING OILS
- A23D7/00—Edible oil or fat compositions containing an aqueous phase, e.g. margarines
- A23D7/02—Edible oil or fat compositions containing an aqueous phase, e.g. margarines characterised by the production or working-up
- A23D7/04—Working-up
- A23D7/05—Working-up characterised by essential cooling
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L3/00—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
- A23L3/36—Freezing; Subsequent thawing; Cooling
- A23L3/361—Freezing; Subsequent thawing; Cooling the materials being transported through or in the apparatus, with or without shaping, e.g. in form of powder, granules, or flakes
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L3/00—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
- A23L3/36—Freezing; Subsequent thawing; Cooling
- A23L3/37—Freezing; Subsequent thawing; Cooling with addition of or treatment with chemicals
- A23L3/375—Freezing; Subsequent thawing; Cooling with addition of or treatment with chemicals with direct contact between the food and the chemical, e.g. liquid nitrogen, at cryogenic temperature
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B9/00—Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point
- F25B9/002—Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point characterised by the refrigerant
- F25B9/008—Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point characterised by the refrigerant the refrigerant being carbon dioxide
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28C—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA COME INTO DIRECT CONTACT WITHOUT CHEMICAL INTERACTION
- F28C3/00—Other direct-contact heat-exchange apparatus
- F28C3/06—Other direct-contact heat-exchange apparatus the heat-exchange media being a liquid and a gas or vapour
- F28C3/08—Other direct-contact heat-exchange apparatus the heat-exchange media being a liquid and a gas or vapour with change of state, e.g. absorption, evaporation, condensation
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B2309/00—Gas cycle refrigeration machines
- F25B2309/06—Compression machines, plants or systems characterised by the refrigerant being carbon dioxide
Definitions
- the present invention relates to a method of cooling of a pumpable liquid with or without particles and an arrangement for carrying trough the cooling.
- Continuous cooling of pumpable liquids usually takes place by means of indirect heat exchange in such a way that the liquid is brought to pass a heat exchanger where it is cooled by cooling media.
- the cooling may take place in tubes or plate heat exchangers, while heat exchangers provided with scrapers are used for more viscous or particle- containing liquids.
- the cooling in the different indirectly working cooling means will necessarily be relatively slow since only a part of the liquid gets in direct contact with the cooled surfaces.
- the method according to the invention is mainly characterized in that a flow of condensed gas is supplied to an amount of said liquid under such conditions that the condensed gas is evapo ⁇ rated, at which the evaporating heat is taken from said liquid, which by reason of that is cooled momentary. A batch of liquid may be cooled in this way. If the cooling should be carried through continuously the flow of condensed gas is directed into a flow of said liquid.
- the gas which is formed during the evaporation is separated from said liquid for example in a separating chamber.
- the liquid with or without particles and the rest of the gas is directed to a second separation chamber according to the invention where the rest of the gas is separated and led away from the liquid with our without particles.
- the separated gas is with advantage compressed and condensed to be used again as a cooling medium.
- the method according to the invention is especially suitable if the liquid with or without particles is used for production of food at which the used gas is approved for food purposes.
- Carbon dioxide is preferably used as such a gas.
- the method is especially useful if liquid with or without particles consists of a viscous liquid which is difficult to cool.
- the method according to the invention is especially suitable when the liquid consists of fat emulsion intended for production of a spreadable fat.
- the said liquid consists of a food mixture comprising particulate material important advantages are also obtained.
- fruit or vegetable mixtures in its own juice or sap as for example cubes of tomato in juice.
- the mixture may also consist of meat or fish pieces in a sauce.
- An arrangement for carrying through the method for cooling according to the invention comprises mainly an inlet for condensed gas and an inlet for pumpable liquid with or without particles, which inlets both lead to a zone with a limited volume in order to obtain a momen ⁇ tary contact between the condensed gas and the liquid with or without particles.
- This zone may with advantage be arranged in an expansion valve or in an expansion chamber connected to a separa ⁇ tion chamber.
- Said separation chamber may by way of a conduit be connected to a compressor for compression of the gas.
- said separation chamber is suitably connected to a further separation chamber which further chamber has an outlet which is connected to a second compressor.
- At least one of the compressors is with advantage connected to a condenser by way of a conduit which condenser in its turn is connected to a storage tank for condensed gas by way of a further conduit from which tank the condensed gas is recirculated for repeated evaporation.
- a condensed gas is brought to evaporate in a pumpable liquid with or without particles.
- the condensed gas almost immediately is evaporated, there is obtained a very rapid cooling of the pumpable liquid.
- the gas to be chosen depends of course on the intended application and its demand for cooling and on the costs which the cooling step may carry. If a more exclusive product shall be rapidly cooled from for example a certain treatment or mixing temperature at or slightly above the room temperature, ethene, Freon or C0 2 may be used. If the cooling takes place at higher temperatures some other gas for example propane, ethane or N 2 0, which condenses at a higher temperature is used.
- the gas must be approved for food.
- carbon dioxide is pre ⁇ ferred even if it is possible to work for example with nitrogen if so should be desired.
- Carbon dioxide condenses at different temperatures depending on the pressure. Accordingly, the condensation temperature is -30 ⁇ C at 14 bar, -0 ⁇ C at 35 bar and 25°C at 60 bar.
- both condensed gas and liquid is supplied to a zone with a limited volume for example in such a way that condensed gas is supplied to the liquid by way of an inlet leading directly into a flow of said liquid.
- the condensed gas is evaporated with a corresponding increase in volume and the said zone must consequently be connected to a space with a larger volume. The temperature of the liquid is lowered directly.
- a flow of fat emulsion with a temperature of 35°C is directed to an evaporating chamber 2 by way of a conduit 1.
- a flow of condensed gas by way of a second conduit 3.
- the condensed gas which consists of C0 2 has a pressure of 40 bar.
- Formed gas and emulsion are then directed further to a separation chamber 4 where a decrease in pressure takes place.
- the largest part of the C0 2 gas which is set free is directed away by way of a conduit 5 with a pressure of 30 bar.
- the mixture of fat emulsion and the rest of the gas is, due to the gravity and the pressure in the chamber 4, brought to pass a second means 6, which only allows flow in one direction into a second chamber 7.
- this second chamber 7 there is a further decrease in pressure such that carbon dioxide gas which is set free leaves the chamber with a pressure of 5 bar through a conduit 8.
- the fat emulsion is brought to pass a further means 9 before it is led to a working unit 10 with a temperature of about 10°C for example to a pin rotor prior to a following packaging.
- the means 6 and 9 may consist of pumps or valves which function as locks which separate the separation chambers from each other and from the following working unit. Carbon dioxide gas may also be led away from the working unit 10.
- the carbon dioxide gas in the conduit 5 with a pressure of 30 bar is led to a compressor 11 where the pressure is increased to 40 bar. From this the gaseous carbon dioxide is led through a conduit 12, 13 to a condenser 14. The compressed gaseous carbon dioxide from the conduit 8 is also directed to the condenser. This gas has been compressed in a compressor 15. In the condenser the temperature is lowered to below 4 ⁇ C, which results in condensation of the gas. From the condenser the condensed carbon dioxide is directed to a storage vessel 16 which functions as a balance vessel. The amount of carbon dioxide which is needed for the cooling is withdrawn from the storage vessel 16 and passes a pump 17 which supplies the condensed gas at a pressure of for example 40 bar. The condensed gas is mixed with new fat emulsion, is evaporated again and is partly removed through the conduit 5. The cooling of the fat emulsion takes place continuously and the carbon dioxide changes state of aggregation cyclically.
- the separation chamber there are used two chambers where the main part of the evaporated carbon dioxide gas is removed from the first chamber, the separation chamber. If so is considered desirable only one common chamber with one outlet for gas may be used. If only one outlet of gas is used the pressure of the C0 2 gas is low which makes degassing of fat emulsion easier but the process will be more expensive.
Abstract
Cooling of a pumpable liquid with or without particles is obtained in that a flow of a condensed gas is supplied to a flow of said liquid during such conditions that the condensed gas is evaporated. The evaporation heat is taken from said liquid which owing to that is cooled momentary. The cooling is carried through in an arrangement comprising an inlet for condensed gas and an inlet for a pumpable liquid with or without particles which both inlets lead to a zone with a limited volume in order to cause momentary contact between condensed gas and said liquid.
Description
Method and arrangement for cooling of a pumpable liquid with our without particles
The present invention relates to a method of cooling of a pumpable liquid with or without particles and an arrangement for carrying trough the cooling.
It is known to cool liquids with or without particles batchwise in different cooling arrangements as cooling tanks with immersion coolers or cooling jackets.
Continuous cooling of pumpable liquids usually takes place by means of indirect heat exchange in such a way that the liquid is brought to pass a heat exchanger where it is cooled by cooling media. For easily flowing liquids the cooling may take place in tubes or plate heat exchangers, while heat exchangers provided with scrapers are used for more viscous or particle- containing liquids.
The cooling in the different indirectly working cooling means will necessarily be relatively slow since only a part of the liquid gets in direct contact with the cooled surfaces.
According to the invention there is now proposed a method for rapid and efficient cooling of a pumpable liquid with or without particles. The method according to the invention is mainly characterized in that a flow of condensed gas is supplied to an amount of said liquid under such conditions that the condensed gas is evapo¬ rated, at which the evaporating heat is taken from said liquid, which by reason of that is cooled momentary. A batch of liquid may be cooled in this way.
If the cooling should be carried through continuously the flow of condensed gas is directed into a flow of said liquid.
The gas which is formed during the evaporation is separated from said liquid for example in a separating chamber.
The liquid with or without particles and the rest of the gas is directed to a second separation chamber according to the invention where the rest of the gas is separated and led away from the liquid with our without particles.
By the fact that the gas is taken away in two steps the separation between the gas and the liquid with or without particles will be more effective.
The separated gas is with advantage compressed and condensed to be used again as a cooling medium.
The method according to the invention is especially suitable if the liquid with or without particles is used for production of food at which the used gas is approved for food purposes. Carbon dioxide is preferably used as such a gas.
The method is especially useful if liquid with or without particles consists of a viscous liquid which is difficult to cool.
The method according to the invention is especially suitable when the liquid consists of fat emulsion intended for production of a spreadable fat.
When the said liquid consists of a food mixture comprising particulate material important advantages are also obtained. As an example of such mixtures there may be mentioned fruit or vegetable mixtures in its own juice or sap as for example cubes of tomato in juice.
The mixture may also consist of meat or fish pieces in a sauce.
An arrangement for carrying through the method for cooling according to the invention comprises mainly an inlet for condensed gas and an inlet for pumpable liquid with or without particles, which inlets both lead to a zone with a limited volume in order to obtain a momen¬ tary contact between the condensed gas and the liquid with or without particles.
As an alternative to this way of converging the flows it is of course also possible to divide both flows such that a small flow of condensed gas is mixed with a little amount of liquid, if so should be desired. The important feature is to obtain the momentary contact between the flows.
This zone may with advantage be arranged in an expansion valve or in an expansion chamber connected to a separa¬ tion chamber.
Said separation chamber may by way of a conduit be connected to a compressor for compression of the gas.
According to the invention said separation chamber is suitably connected to a further separation chamber which further chamber has an outlet which is connected to a second compressor.
At least one of the compressors is with advantage connected to a condenser by way of a conduit which condenser in its turn is connected to a storage tank for condensed gas by way of a further conduit from which tank the condensed gas is recirculated for repeated evaporation.
According to the method of the invention a condensed gas is brought to evaporate in a pumpable liquid with or without particles. By the fact that the condensed gas almost immediately is evaporated, there is obtained a very rapid cooling of the pumpable liquid. The gas to be chosen depends of course on the intended application and its demand for cooling and on the costs which the cooling step may carry. If a more exclusive product shall be rapidly cooled from for example a certain treatment or mixing temperature at or slightly above the room temperature, ethene, Freon or C02 may be used. If the cooling takes place at higher temperatures some other gas for example propane, ethane or N20, which condenses at a higher temperature is used.
If the pumpable liquid with or without particles shall be used for production of a food product the gas must be approved for food. As such gas carbon dioxide is pre¬ ferred even if it is possible to work for example with nitrogen if so should be desired. Carbon dioxide condenses at different temperatures depending on the pressure. Accordingly, the condensation temperature is -30βC at 14 bar, -0βC at 35 bar and 25°C at 60 bar.
Working with higher pressure than 40 bar usually makes the process more expensive in an unnecessarily high degree.
In order to make the contact between the condensed gas and the liquid which shall be cooled as intensive as possible, both condensed gas and liquid is supplied to a zone with a limited volume for example in such a way that condensed gas is supplied to the liquid by way of an inlet leading directly into a flow of said liquid. Immediately after the mixing the condensed gas is evaporated with a corresponding increase in volume and the said zone must consequently be connected to a space with a larger volume. The temperature of the liquid is lowered directly. As a consequence of the decrease in pressure and the expansion, the liquid is during this rapid course also exposed to a mechanic treatment as a consequence of the high shear forces which are deve- loped. In the separation chamber a pressure decrease takes place and a part of the gas is removed.
The invention is described further with reference to the attached drawing which schematically shows an embodiment of an arrangement for cooling of a fat emulsion chosen as an example.
A flow of fat emulsion with a temperature of 35°C is directed to an evaporating chamber 2 by way of a conduit 1. To the chamber there is also directed a flow of condensed gas by way of a second conduit 3. The condensed gas, which consists of C02 has a pressure of 40 bar. When the condensed gas enters the expansion chamber and is brought together with the fat emulsion it is immediately evaporated with a simultaneous cooling of the fat emulsion. Formed gas and emulsion are then directed further to a separation chamber 4 where a decrease in pressure takes place. The largest part of the C02 gas which is set free is directed away by way of a conduit 5 with a pressure of 30 bar. The mixture of
fat emulsion and the rest of the gas is, due to the gravity and the pressure in the chamber 4, brought to pass a second means 6, which only allows flow in one direction into a second chamber 7. In this second chamber 7 there is a further decrease in pressure such that carbon dioxide gas which is set free leaves the chamber with a pressure of 5 bar through a conduit 8. The fat emulsion is brought to pass a further means 9 before it is led to a working unit 10 with a temperature of about 10°C for example to a pin rotor prior to a following packaging. The means 6 and 9 may consist of pumps or valves which function as locks which separate the separation chambers from each other and from the following working unit. Carbon dioxide gas may also be led away from the working unit 10.
The carbon dioxide gas in the conduit 5 with a pressure of 30 bar is led to a compressor 11 where the pressure is increased to 40 bar. From this the gaseous carbon dioxide is led through a conduit 12, 13 to a condenser 14. The compressed gaseous carbon dioxide from the conduit 8 is also directed to the condenser. This gas has been compressed in a compressor 15. In the condenser the temperature is lowered to below 4βC, which results in condensation of the gas. From the condenser the condensed carbon dioxide is directed to a storage vessel 16 which functions as a balance vessel. The amount of carbon dioxide which is needed for the cooling is withdrawn from the storage vessel 16 and passes a pump 17 which supplies the condensed gas at a pressure of for example 40 bar. The condensed gas is mixed with new fat emulsion, is evaporated again and is partly removed through the conduit 5.
The cooling of the fat emulsion takes place continuously and the carbon dioxide changes state of aggregation cyclically.
In the shown embodiment there are used two chambers where the main part of the evaporated carbon dioxide gas is removed from the first chamber, the separation chamber. If so is considered desirable only one common chamber with one outlet for gas may be used. If only one outlet of gas is used the pressure of the C02 gas is low which makes degassing of fat emulsion easier but the process will be more expensive.
In the shown embodiment condensed carbon dioxide with a pressure of 40 bar has been used for the cooling.
The values of the gas pressure which are shown on the drawing only represent examples of a pressure level which is usable for the invention. Many other alterna- tives are possible also at pressures over 40 bar where different combinations of pressure and temperature of the condensed gas with values over 40 bar/4°C may be used.
If the removed carbon dioxide is compressed to a higher pressure a smaller cooling area in the condenser is needed than if the pressure is lower.
An arrangement of the described kind presents large advantages in relation to earlier known technique where scraped-surface heat exchangers have taken care of the cooling. If some problem should arise at the packaging the feed of fat emulsion and condensed carbon dioxide to the evaporation chamber is interrupted. When the problem has been solved, often only some minute later, the
feeding starts again and the cooling process continues. A corresponding interruption in a plant with scraped- surface heat exchanger may result in total stop of the operation. Only after cleaning a re-start may be possible.
Within the scope of the invention it is possible to use as well other gases approved for food, if the pumpable liquid with or without particles consists of a food product or shall be treated further to such a product, as other kinds of gases with suitable condensation temperatures for other types of liquids.
Claims
1. Method for cooling of a pumpable liquid with or without particles, c h a r a c t e r i z e d i n that a flow of condensed gas is directed to an amount of said liquid during such conditions that the condensed gas is evaporated, at which the evaporation heat is taken from the liquid with or without particles which liquid owing to that is cooled momentary.
2. Method according to claim 1, c h a r a c t e ¬ r i z e i n that the cooling takes place continuously by directing the flow of condensed gas into a flow of said liquid.
3. Method according to claim 2, c h a r a c t e ¬ r i z e d i n that the gas which is formed during the evaporation is separated from said liquid in a separation chamber.
4. Method according to claim 1-3, c h a r a c t e ¬ r i z e d i n that said liquid and the rest of the gas are directed to a second separation chamber where the remaining gas is separated and removed from said liquid.
5. Method according to claim 4, c h a r a c t e ¬ r i z e i n that the separated gas is compressed and condensed in order to be used again as a cooling medium.
6. Method according to any one of the preceding claims, c h a r a c t e r i z e d i n that said liquid is used for production of a food and in that the used gas is approved for food.
7. Method according to claim 6, c h a r a c t e ¬ r i z e d i n that the gas consists of carbon dioxide.
8. Method according to claim 1-7, c h a r a c t e ¬ r i z e d i n that the said liquid consists of a fat emulsion intended for production of a spreadable fat.
9. Method according to claim 1-7, c h a r a c t e - r i z e d i n that said liquid consists of a food mixture comprising particulate material.
10. Arrangement for carrying through the method for cooling according to claim 1, c h a r a c t e - r i z e d i n that the arrangement comprises an inlet for condensed gas and an inlet for pumpable liquid with or without particles, which inlets both lead to a zone with limited volume in order to create a momentary contact between condensed gas and said liquid.
11. Arrangement according to claim 10, c h a r a c ¬ t e r i z e d i n that said zone is arranged in an expansion valve or in an expansion chamber ( 2 ) connected to a separation chamber (4 ) .
12. Arrangement according to claim 10-11, c h a ¬ r a c t e r i z e d i n that the separation chamber (4) is connected to a compressor (11) for compressing of the gas by way of a conduit.
13. Arrangement according to claim 10-12, c h a ¬ r a c t e r i z e d i n that the said separation chamber (4) is connected to a further separation chamber (7) , which further chamber also has an outlet for gas which is connected to a second compressor (15).
14. Arrangement according to claim 12 or 13, c h a ¬ r a c t e r i z e d i n that at least one of the compressors is connected to a condenser (14) by way of a conduit, which in its turn is connected to a storage tank (16) for condensed gas by way of a further conduit from which tank the condensed gas is recirculated for repeated evaporation.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU43601/96A AU4360196A (en) | 1994-12-23 | 1995-12-21 | Method and arrangement for cooling of a pumpable liquid with or without particles |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SE9404499-7 | 1994-12-23 | ||
SE9404499A SE509920C2 (en) | 1994-12-23 | 1994-12-23 | Method and apparatus for continuous cooling of a pumpable emulsion or suspension |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1996019922A1 true WO1996019922A1 (en) | 1996-07-04 |
Family
ID=20396461
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/SE1995/001556 WO1996019922A1 (en) | 1994-12-23 | 1995-12-21 | Method and arrangement for cooling of a pumpable liquid with or without particles |
Country Status (3)
Country | Link |
---|---|
AU (1) | AU4360196A (en) |
SE (1) | SE509920C2 (en) |
WO (1) | WO1996019922A1 (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1999022855A1 (en) * | 1997-10-31 | 1999-05-14 | Messer Griesheim Gmbh | Method and device for cooling and atomizing liquid or paste-like substances |
WO1999065600A1 (en) * | 1998-06-02 | 1999-12-23 | Leiv Eiriksson Nyfotek As | A method for formulating particles |
EP1097916A2 (en) * | 1999-11-05 | 2001-05-09 | Nippon Shokubai Co., Ltd. | Method for production of acrylic acid and apparatus for production of acrylic acid |
WO2005053440A1 (en) * | 2003-12-03 | 2005-06-16 | L'air Liquide, Societe Anonyme A Directoire Et Conseil De Surveillance Pour L'etude Et L'exploitation Des Procedes Georges Claude | Method and plant for cooling fluids by direct contact with liquefied gases |
Citations (7)
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DE864355C (en) * | 1939-05-27 | 1953-01-26 | James Dr Senn | Method and device for the production of butter by processing the butter-containing material in the presence of a CO-containing gas |
US4000332A (en) * | 1972-12-15 | 1976-12-28 | Mjolkcentralen, Ekonomisk Forening | High protein low calorie dairy spread and its production |
US4217372A (en) * | 1969-09-11 | 1980-08-12 | Ebskamp Hermanus J G | Method for improving the structural properties of fats |
US4267015A (en) * | 1978-04-11 | 1981-05-12 | Ciboit Jacques J | Process for cooling hot concentrated milk coming from an evaporator, by expansion by stages |
US4362758A (en) * | 1980-09-30 | 1982-12-07 | Lever Brothers Company | Process for producing a low-calorie spread |
WO1991006220A1 (en) * | 1989-11-07 | 1991-05-16 | Skånemejerier Ekonomisk Förening | Edible-fat product with low fat content, and method for the production thereof |
WO1992008363A1 (en) * | 1990-11-13 | 1992-05-29 | Portwall Pty. Limited | Lipid fractionation and products so obtained |
-
1994
- 1994-12-23 SE SE9404499A patent/SE509920C2/en not_active IP Right Cessation
-
1995
- 1995-12-21 AU AU43601/96A patent/AU4360196A/en not_active Abandoned
- 1995-12-21 WO PCT/SE1995/001556 patent/WO1996019922A1/en active Application Filing
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
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DE864355C (en) * | 1939-05-27 | 1953-01-26 | James Dr Senn | Method and device for the production of butter by processing the butter-containing material in the presence of a CO-containing gas |
US4217372A (en) * | 1969-09-11 | 1980-08-12 | Ebskamp Hermanus J G | Method for improving the structural properties of fats |
US4000332A (en) * | 1972-12-15 | 1976-12-28 | Mjolkcentralen, Ekonomisk Forening | High protein low calorie dairy spread and its production |
US4267015A (en) * | 1978-04-11 | 1981-05-12 | Ciboit Jacques J | Process for cooling hot concentrated milk coming from an evaporator, by expansion by stages |
US4362758A (en) * | 1980-09-30 | 1982-12-07 | Lever Brothers Company | Process for producing a low-calorie spread |
WO1991006220A1 (en) * | 1989-11-07 | 1991-05-16 | Skånemejerier Ekonomisk Förening | Edible-fat product with low fat content, and method for the production thereof |
WO1992008363A1 (en) * | 1990-11-13 | 1992-05-29 | Portwall Pty. Limited | Lipid fractionation and products so obtained |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1999022855A1 (en) * | 1997-10-31 | 1999-05-14 | Messer Griesheim Gmbh | Method and device for cooling and atomizing liquid or paste-like substances |
WO1999065600A1 (en) * | 1998-06-02 | 1999-12-23 | Leiv Eiriksson Nyfotek As | A method for formulating particles |
EP1097916A2 (en) * | 1999-11-05 | 2001-05-09 | Nippon Shokubai Co., Ltd. | Method for production of acrylic acid and apparatus for production of acrylic acid |
EP1097916A3 (en) * | 1999-11-05 | 2002-04-17 | Nippon Shokubai Co., Ltd. | Method for production of acrylic acid and apparatus for production of acrylic acid |
US7541490B2 (en) | 1999-11-05 | 2009-06-02 | Nippon Shokubai Co., Ltd. | Method for production of acrylic acid and apparatus for production of acrylic acid |
WO2005053440A1 (en) * | 2003-12-03 | 2005-06-16 | L'air Liquide, Societe Anonyme A Directoire Et Conseil De Surveillance Pour L'etude Et L'exploitation Des Procedes Georges Claude | Method and plant for cooling fluids by direct contact with liquefied gases |
AU2004294805B2 (en) * | 2003-12-03 | 2010-04-22 | L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Method and plant for cooling fluids by direct contact with liquefied gases |
Also Published As
Publication number | Publication date |
---|---|
SE9404499D0 (en) | 1994-12-23 |
SE509920C2 (en) | 1999-03-22 |
SE9404499L (en) | 1996-06-24 |
AU4360196A (en) | 1996-07-19 |
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