Structured Fluids: Polymers, Colloids, SurfactantsPublisher Description |
Contents
Overview | 1 |
12 A gallery of structured fluids | 2 |
122 Rheology | 4 |
123 Scaling | 5 |
13 Types of structured fluids | 6 |
132 Aggregates | 7 |
134 Surfactant assemblies | 9 |
135 Association | 10 |
514 Depletion forces | 120 |
52 Repulsive forces | 122 |
521 Steric stabilization | 123 |
522 Electrostatic stabilization | 127 |
53 Organized states | 132 |
532 Lyotropic liquid crystals | 133 |
533 Fractal aggregates | 134 |
54 Colloidal motion | 135 |
14 The chapters to follow | 11 |
Fundamentals | 13 |
212 Probability and work | 17 |
213 Lattice gas | 22 |
214 Approach to equilibrium | 24 |
22 Magnitude of a liquids response | 27 |
23 Experimental probes of structured fluids | 31 |
232 Probes of spatial structure | 34 |
233 Probes of atomic environment | 38 |
Solution to Problem 21 | 39 |
References | 40 |
Polymer molecules | 41 |
311 Monomers | 42 |
312 Architecture | 43 |
313 Polymerization | 45 |
32 Randomwalk polymer | 47 |
321 Endtoend probability | 48 |
33 Interior structure | 54 |
331 Scattering | 56 |
34 Selfavoidance and selfinteraction | 61 |
341 Local and global avoidance | 62 |
343 Selfinteraction and solvent quality | 67 |
344 Universal ratios | 72 |
345 Polyelectrolytes | 73 |
Dilation symmetry | 75 |
Polymeric solvents and screening | 79 |
References | 82 |
Polymer solutions | 83 |
42 Semidilute solutions | 85 |
421 Structure | 86 |
422 Energy | 87 |
423 Concentrated solutions and melts | 90 |
432 Intrinsic viscosity | 94 |
434 Internal fluctuations | 98 |
436 Semidilute diffusion | 99 |
437 Semidilute selfdiffusion without entanglement | 102 |
438 Motion with entanglements | 103 |
439 Stress relaxation and viscosity | 105 |
44 Conclusion | 109 |
Solution to Problem 45 Deriving permeability | 110 |
References | 111 |
Colloids | 113 |
why colloids are sticky | 114 |
512 Solid bodies | 116 |
513 PerturbationAttraction Theorem | 117 |
541 Electrophoresis | 136 |
542 Soret effect | 137 |
Colloidal aggregates | 139 |
Simplest aggregation model | 141 |
References | 149 |
Interfaces | 151 |
62 Simple fluids | 153 |
622 Contact angle | 156 |
623 Wetting dynamics | 158 |
624 Surface heterogeneity | 159 |
625 Other interfacial flows | 160 |
63 Solutes and interfacial tension | 161 |
631 Fluid mixtures | 162 |
64 Polyatomic solutes | 163 |
642 Concentration profile | 165 |
643 Hard wall | 167 |
644 Kinetics of adsorption | 168 |
| 171 | |
Surfactants | 173 |
72 Mixing principles | 174 |
721 Positivity | 175 |
like dissolves like | 176 |
725 Transitivity | 177 |
73 Surfactant molecules | 178 |
micelles | 180 |
wormlike micelles | 182 |
twodimensional micelles | 185 |
75 Micelle interaction | 186 |
751 Energy of twodimensional micelles | 188 |
752 Energy to confine a fluctuating membrane | 191 |
microemulsions | 192 |
761 Interfacial tension | 195 |
77 Amphiphilic polymers | 198 |
771 Micelle size | 199 |
772 Other copolymers | 201 |
773 Polymeric amphiphiles in solution | 202 |
78 Dynamics and rheology | 203 |
781 Wormlike entanglement and relaxation | 204 |
782 Rheology of lamellar solution | 206 |
783 Shearinduced restructuring | 207 |
GaussBonnet Theorem | 210 |
References | 211 |
Index | 213 |
Other editions - View all
Structured Fluids: Polymers, Colloids, Surfactants Thomas A. Witten,T. Witten,P. A. Pincus,P. Pincus Limited preview - 2004 |
Structured Fluids: Polymers, Colloids, Surfactants Thomas A. Witten,Philip A. Pincus No preview available - 2010 |
Common terms and phrases
adsorbed adsorption aggregates amphiphilic angle asymptotic atoms attraction average b₂ behavior blobs Boltzmann bonds Brownian motion chain Chapter charge cluster colloidal particles concentration configuration consider contact angle copolymers curvature deformation density depends diffusion constant discussed dispersed dissipation distance droplets effect elastic end-to-end equation equilibrium example factor finite flow fluctuations force fractal dimension free energy given hydrocarbon hydrodynamic immiscible increases independent interaction interface interfacial energy interfacial tension ions larger lattice layer length liquid microemulsion miscible modulus molecular weight molecules monomers motion nanometer Oseen tensor osmotic pressure persistence length perturbation phase Phys polarizability polymer solution polymerization polystyrene probability properties radius random random-walk polymer region relaxation reptation repulsion roughly scaling scattering screening segments self-avoiding shear rate simple solvent spatial sphere spherical stress structured fluids subsystem surface surfactant temperature thermal typical velocity viscosity volume fraction Waals wormlike micelles